Generalized Clausius relation and power dissipation in nonequilibrium stochastic systems.

نویسندگان

  • B Gaveau
  • M Moreau
  • L S Schulman
چکیده

In the framework of the stochastic dynamics of open Markov systems, we derive an extension of the Clausius inequality for transitions between states of the system. We give a formula for the power produced when the system is in its stationary state and relate it to the dissipation of energy needed to maintain the system out of equilibrium. We deduce that, near equilibrium, maximal power production requires an energy dissipation of the same order of magnitude as the power production.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

The Thermodynamics of Small Driven Systems

In the present thesis, a thermodynamic theory is developed for driven soft matter systems like polymer solutions and colloidal suspensions. Within this theory, notions like the work applied to the system externally and the heat dissipated into a heat reservoir will be defined consistently. Going beyond mean values, all quantities are defined along a single trajectory. This thermodynamic approac...

متن کامل

Nonadiabatic entropy production for non-Markov dynamics.

We extend the definition of nonadiabatic entropy production given for Markovian systems by Esposito and Van den Broeck [Phys. Rev. Lett. 104, 090601 (2010)], to arbitrary non-Markov ergodic dynamics. We also introduce a notion of stability characterizing non-Markovianity. For stable non-Markovian systems, the nonadiabatic entropy production satisfies an integral fluctuation theorem, leading to ...

متن کامل

Generalized clausius inequality for nonequilibrium quantum processes.

We show that the nonequilibrium entropy production for a driven quantum system is larger than the Bures length, the geometric distance between its actual state and the corresponding equilibrium state. This universal lower bound generalizes the Clausius inequality to arbitrary nonequilibrium processes beyond linear response. We further derive a fundamental upper bound for the quantum entropy pro...

متن کامل

Fluctuations in stationary nonequilibrium states of irreversible processes.

We formulate a dynamical fluctuation theory for stationary nonequilibrium states (SNS) which covers situations in a nonlinear hydrodynamic regime and is verified explicitly in stochastic models of interacting particles. In our theory a crucial role is played by the time reversed dynamics. Our results include the modification of the Onsager-Machlup theory in the SNS, a general Hamilton-Jacobi eq...

متن کامل

Dissipation, generalized free energy, and a self-consistent nonequilibrium thermodynamics of chemically driven open subsystems.

Nonequilibrium thermodynamics of a system situated in a sustained environment with influx and efflux is usually treated as a subsystem in a larger, closed "universe." A question remains with regard to what the minimally required description for the surrounding of such an open driven system is so that its nonequilibrium thermodynamics can be established solely based on the internal stochastic ki...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Physical review. E, Statistical, nonlinear, and soft matter physics

دوره 79 1 Pt 1  شماره 

صفحات  -

تاریخ انتشار 2009